Substituent effects on the photolysis of methyl 2-carboxylate substituted aliphatic 2H-azirines

In this study, the UV induced photochemical reactions of two 2H-azirines - methyl 2-chloro-3-methyl-2H-azirine-2-carboxylate (MCMAC) and methyl 3-methyl-2H-azirine-2-carboxylate (MMAC) - isolated in argon matrices are compared. For both compounds, irradiation with [lambda] > 235 nm led to observa...

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Bibliographic Details
Main Author: Gómez-Zavaglia, Andrea (author)
Other Authors: Kaczor, Agnieszka (author), Cardoso, Ana L. (author), Melo, Teresa M. V. D. Pinho e (author), Fausto, Rui (author)
Format: article
Language:eng
Published: 2007
Subjects:
2H-azirines
Photolysis
Matrix isolation FTIR spectroscopy
Substituent effects
Online Access:http://hdl.handle.net/10316/5044
Country:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/5044

Internet

http://hdl.handle.net/10316/5044

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