Substituent effects on the photolysis of methyl 2-carboxylate substituted aliphatic 2H-azirines

In this study, the UV induced photochemical reactions of two 2H-azirines - methyl 2-chloro-3-methyl-2H-azirine-2-carboxylate (MCMAC) and methyl 3-methyl-2H-azirine-2-carboxylate (MMAC) - isolated in argon matrices are compared. For both compounds, irradiation with [lambda] > 235 nm led to observa...

ver descrição completa

Detalhes bibliográficos
Autor principal: Gómez-Zavaglia, Andrea (author)
Outros Autores: Kaczor, Agnieszka (author), Cardoso, Ana L. (author), Melo, Teresa M. V. D. Pinho e (author), Fausto, Rui (author)
Formato: article
Idioma:eng
Publicado em: 2007
Assuntos:
2H-azirines
Photolysis
Matrix isolation FTIR spectroscopy
Substituent effects
Texto completo:http://hdl.handle.net/10316/5044
País:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/5044

Texto Completo

http://hdl.handle.net/10316/5044

Registros relacionados