Synthesis of fluorescent 2-(2´,2´´-bithienyl)-1,3-benzothiazoles

Eight new bithienyl benzothiazole derivatives 1 were synthesised by reacting various 5-formyl-5´-alkoxy- or 5-formyl-5´-amino-2,2´-bithiophenes 2 with ortho-aminobenzenethiol in good to excelent yields. Compounds 1a-h were completely characterised by spectroscopic methods. Absorption and fluorescenc...

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Bibliographic Details
Main Author: Batista, Rosa Maria Ferreira (author)
Other Authors: Costa, Susana P. G. (author), Raposo, M. Manuela M. (author)
Format: conferencePaper
Language:eng
Published: 2003
Subjects:
Online Access:http://hdl.handle.net/1822/1972
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/1972
Description
Summary:Eight new bithienyl benzothiazole derivatives 1 were synthesised by reacting various 5-formyl-5´-alkoxy- or 5-formyl-5´-amino-2,2´-bithiophenes 2 with ortho-aminobenzenethiol in good to excelent yields. Compounds 1a-h were completely characterised by spectroscopic methods. Absorption and fluorescence spectra of these compounds were also recorded. In agreement with previous findings concerning the fluorescence studies of 2-(2´-thienyl)-1,3-benzothiazoles, the new compounds prepared can find application for additives in textile dyeing and plastics, tunable dye lasers, biological stains, fluorescent markers, materials science and optoelectronics.