Cis→trans conversion of formic acid by dissipative tunneling in solid rare gases: Influence of environment on the tunneling rate.
The relaxation of the higher-energy cis conformer of formic acid to the lower-energy trans form by a tunneling mechanism has been investigated in low-temperature rare gas matrices. In the temperature range 8–60 K, the tunneling takes place dominantly from the vibrational ground state of the cis form...
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Detalhes bibliográficos
| Autor principal: |
Pettersson, M.
(author) |
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| Outros Autores: |
Maçôas, E. M. S.
(author),
Khriachtchev, L.
(author),
Lundell, J.
(author),
Fausto, R.
(author),
Räsänen, M.
(author) |
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| Formato: | article
|
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| Idioma: | eng |
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| Publicado em: |
2002
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| Texto completo: | http://hdl.handle.net/10316/17785
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| País: | Portugal
|
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| Oai: | oai:estudogeral.sib.uc.pt:10316/17785 |
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