Cis→trans conversion of formic acid by dissipative tunneling in solid rare gases: Influence of environment on the tunneling rate.
The relaxation of the higher-energy cis conformer of formic acid to the lower-energy trans form by a tunneling mechanism has been investigated in low-temperature rare gas matrices. In the temperature range 8–60 K, the tunneling takes place dominantly from the vibrational ground state of the cis form...
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| Other Authors: | , , , , |
| Format: | article |
| Language: | eng |
| Published: |
2002
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| Online Access: | http://hdl.handle.net/10316/17785 |
| Country: | Portugal |
| Oai: | oai:estudogeral.sib.uc.pt:10316/17785 |