Effect of filler content on morphology and physical-chemical characteristics of poly(vinylidene fluoride)/NaY zeolite-filled membranes

Poly(vinylidene fluoride) electrospun membranes have been prepared with different NaY zeolite contents up to 32 wt%. Inclusion of zeolites induces an increase of average fiber size from ~200 nm in the pure polymer up to ~500 nm in the composite with 16 wt% zeolite content. For higher filler contents...

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Bibliographic Details
Main Author: Lopes, A. C. (author)
Other Authors: Ribeiro, C. (author), Sencadas, Vítor João Gomes Silva (author), Botelho, Gabriela (author), Lanceros-Méndez, S. (author)
Format: article
Language:eng
Published: 2014
Subjects:
Online Access:http://hdl.handle.net/1822/31990
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/31990
Description
Summary:Poly(vinylidene fluoride) electrospun membranes have been prepared with different NaY zeolite contents up to 32 wt%. Inclusion of zeolites induces an increase of average fiber size from ~200 nm in the pure polymer up to ~500 nm in the composite with 16 wt% zeolite content. For higher filler contents, a wider distribution of fibers occurs leading to a broader size distribution between the previous fiber size values. Hydrophobicity of the membranes increases from ~115º water contact angle to ~128º with the addition of the filler and is independent on filler content, indicating a wrapping of the zeolite by the polymer. The water contact angle further increases with fiber alignment up to ~137°. Electrospun membranes are formed with ~80 % of the polymer crystalline phase in the electroactive β phase, independently on the electrospinning processing conditions or filler content. Viability of MC3T3-E1 cells on the composite membranes after 72 h of cell culture indicates the suitability of the membranes for tissue engineering applications.