Phosphotungstates as catalysts for monoterpenes oxidation: Homo- and heterogeneous performance

Lacunary (PW11), mono-substituted (PW11M) and sandwich type M-4(PW9)(2) phosphotungstates (M = Co-II, Fe-III) exhibits high catalytic activity for geraniol and R-(+)-limonene oxidation under mild conditions, using hydrogen peroxide as oxidant and acetonitrile as solvent. The best homogeneous perform...

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Bibliographic Details
Main Author: Balula, Salete S. (author)
Other Authors: Santos, Isabel C. M. S. (author), Cunha-Silva, Luis (author), Carvalho, Ana P. (author), Pires, Joao (author), Freire, Cristina (author), Cavaleiro, Jose A. S. (author), de Castro, Baltazar (author), Cavaleiro, Ana M. V. (author)
Format: article
Language:eng
Published: 1000
Subjects:
IRON-SUBSTITUTED POLYOXOTUNGSTATES
KEGGIN-TYPE POLYOXOTUNGSTATES
HYDROGEN-PEROXIDE
MESOPOROUS SILICA
PORPHYRIN COMPLEXES
CRYSTAL-STRUCTURE
POLYOXOMETALATE
EPOXIDATION
TUNGSTOPHOSPHATES
MOLYBDENUM(VI)
Online Access:http://hdl.handle.net/10773/20977
Country:Portugal
Oai:oai:ria.ua.pt:10773/20977

Internet

http://hdl.handle.net/10773/20977

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