Polymerization of ɛ-caprolactone using ruthenium(II) mixed metallocene catalysts and isopropyl alcohol: Living character and mechanistic study
A series of ruthenium(II) complexes with the general formula [Ru(η5-C5H5) (η6-substituted arene)]+[PF6]− (substituted arene = 2-phenylpyridine (1), dibenzosuberone (2) and toluene (3)), in combination with isopropyl alcohol were used for the polymerization of ɛ-caprolactone. The polymerization was f...
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| Format: | article |
| Language: | eng |
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2012
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| Online Access: | http://hdl.handle.net/10174/3552 |
| Country: | Portugal |
| Oai: | oai:dspace.uevora.pt:10174/3552 |