Polymerization of ɛ-caprolactone using ruthenium(II) mixed metallocene catalysts and isopropyl alcohol: Living character and mechanistic study
A series of ruthenium(II) complexes with the general formula [Ru(η5-C5H5) (η6-substituted arene)]+[PF6]− (substituted arene = 2-phenylpyridine (1), dibenzosuberone (2) and toluene (3)), in combination with isopropyl alcohol were used for the polymerization of ɛ-caprolactone. The polymerization was f...
| Autor principal: | |
|---|---|
| Formato: | article |
| Idioma: | eng |
| Publicado em: |
2012
|
| Assuntos: | |
| Texto completo: | http://hdl.handle.net/10174/3552 |
| País: | Portugal |
| Oai: | oai:dspace.uevora.pt:10174/3552 |