Cobalt complexes bearing scorpionate ligands: Synthesis, characterization, cytotoxicity and DNA cleavage

A number of novel, water-stable redox-active cobalt complexes of the C-functionalized tripodal ligands tris(pyrazolyl)methane XC(pz)(3) (X = HOCH2, CH2OCH2Py or CH2OSO2Me) are reported along with their effects on DNA. The compounds were isolated as air-stable solids and fully characterized by IR and...

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Detalhes bibliográficos
Autor principal: Silva, Telma F. S. (author)
Outros Autores: Martins, Luisa (author), Guedes da Silva, Maria de Fátima (author), Fernandes, Alexandra R. (author), Silva, Ana (author), Borralho, Pedro M. (author), Santos, Susana (author), Rodrigues, Cecília M. P. (author), Pombeiro, Armando (author)
Formato: article
Idioma:eng
Publicado em: 2015
Assuntos:
Single-pot hydrocarboxylation
Organic molecular-crystals
Peroxidative oxidation
Carboxylic-acids
Metal-free
In-vitro
Tris(Pyrazolyl)Methane ligands
Aqueous systems
Mild conditions
Water clusters
Texto completo:http://hdl.handle.net/10400.21/5097
País:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/5097

Texto Completo

http://hdl.handle.net/10400.21/5097

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