Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]

A simple and mild (room temperature) process for oxidation of o-, m- or p-xylene to the corresponding methylbenzyl alcohols, tolualdehydes and toluic acids, using H2O2 (30% aqueous solution) and the iron(II) C-scorpionate [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) catalyst is presented. Remarkably, aft...

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Detalhes bibliográficos
Autor principal: Mendes, Marta (author)
Outros Autores: Da Costa Ribeiro, Ana Paula (author), Alegria, Elisabete (author), Martins, Luisa (author), Pombeiro, Armando (author)
Formato: article
Idioma:eng
Publicado em: 2017
Assuntos:
Xylene
Oxidation
Scorpionate
Iron
Hydrogen peroxide
Texto completo:http://hdl.handle.net/10400.21/6990
País:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/6990

Texto Completo

http://hdl.handle.net/10400.21/6990

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