Homogeneous Catalytic Oxidation of Olefins with Hydrogen Peroxide in the Presence of a Manganese-Substituted Polyoxomolybdate

[PMo11Mn(H2O)O-39](5-) is used as catalyst in the homogeneous oxidation of cis-cyclooctene, cyclohexene, styrene, and geraniol with H2O2 in acetonitrile. Oxidation of cis-cyclooctene gives only cyclooctene oxide; cyclohexene-1,2-diol is the main product for cyclohexene; styrene is preferentially oxi...

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Bibliographic Details
Main Author: Duarte, Tiago A. G. (author)
Other Authors: Santos, Isabel C. M. S. (author), Simoes, Mario M. Q. (author), Neves, M. Graca P. M. S. (author), Cavaleiro, Ana M. V. (author), Cavaleiro, Jose A. S. (author)
Format: article
Language:eng
Published: 1000
Subjects:
KEGGIN-TYPE POLYOXOMOLYBDATES
SELECTIVE OXIDATION
MOLECULAR-OXYGEN
BIFUNCTIONAL CATALYSTS
POLYOXOTUNGSTATES
MONOTERPENES
EPOXIDATION
CHEMISTRY
ALCOHOLS
ALKENES
Online Access:http://hdl.handle.net/10773/20840
Country:Portugal
Oai:oai:ria.ua.pt:10773/20840
Description
Summary:[PMo11Mn(H2O)O-39](5-) is used as catalyst in the homogeneous oxidation of cis-cyclooctene, cyclohexene, styrene, and geraniol with H2O2 in acetonitrile. Oxidation of cis-cyclooctene gives only cyclooctene oxide; cyclohexene-1,2-diol is the main product for cyclohexene; styrene is preferentially oxidized to benzaldehyde; a TOF almost as high as 28800 h(-1) is reached for geraniol oxidation.

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