Intercalation of a molybdenum eta(3)-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation

A Zn-Al layered double hydroxide (LDH) intercalated by [Mo(eta(3)-C3H5)Cl(CO)(2)(bpdc)](2-) anions (bpdc = 2,2'-bipyridine-5,5'-dicarboxylate) has been prepared by coprecipitation from aqueous solution and characterised by various techniques. The one-pot method gives rise to a highly organ...

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Bibliographic Details
Main Author: Gomes, Ana C. (author)
Other Authors: Bruno, Sofia M. (author), Gamelas, Carla A. (author), Valente, Anabela A. (author), Abrantes, Marta (author), Goncalves, Isabel S. (author), Romao, Carlos C. (author), Pillinger, Martyn (author)
Format: article
Language:eng
Published: 1000
Subjects:
TERT-BUTYL HYDROPEROXIDE
METAL-CARBONYL CLUSTERS
N-H GROUPS
TUNGSTEN COMPLEXES
CRYSTAL-STRUCTURE
MO-II
STRUCTURAL-CHARACTERIZATION
CYCLOOCTENE EPOXIDATION
IMMOBILIZATION
PRECURSORS
Online Access:http://hdl.handle.net/10773/20175
Country:Portugal
Oai:oai:ria.ua.pt:10773/20175

Internet

http://hdl.handle.net/10773/20175

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