Synthesis and catalytic properties in olefin epoxidation of octahedral dichloridodioxidomolybdenum(VI) complexes bearing N,N-dialkylamide ligands: crystal structure of [Mo2O4(mu(2)-O)Cl-2(dmf)(4)]

The catalytic performance of the complexes [MoO2Cl2(L)2][L = N,N-dimethylformamide (dmf), N,N-dimethylacetamide(dma), N,N-dimethylpropionamide (dmpa), N,N-diethylformamide(def) and N,N-diphenylformamide (dpf)] was examined in the epoxidation of cis-cyclooctene with tert-butyl hydroperoxide(tbhp) at...

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Bibliographic Details
Main Author: Gago, Sandra (author)
Other Authors: Neves, Patrícia (author), Monteiro, Bernardo (author), Pessêgo, Márcia (author), Lopes, Andre D. (author), Valente, Anabela A. (author), Almeida Paz, Filipe A. (author), Pillinger, Martyn (author), Moreira, José (author), Silva, Carlos M. (author), Gonçalves, Isabel S. (author)
Format: article
Language:eng
Published: 2013
Subjects:
Molybdenum
O ligands
Homogeneous catalysis
Epoxidation
Kinetics
Online Access:http://hdl.handle.net/10400.1/3227
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/3227

Internet

http://hdl.handle.net/10400.1/3227

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