Synthesis and catalytic properties in olefin epoxidation of octahedral dichloridodioxidomolybdenum(VI) complexes bearing N,N-dialkylamide ligands: crystal structure of [Mo2O4(mu(2)-O)Cl-2(dmf)(4)]

The catalytic performance of the complexes [MoO2Cl2(L)2][L = N,N-dimethylformamide (dmf), N,N-dimethylacetamide(dma), N,N-dimethylpropionamide (dmpa), N,N-diethylformamide(def) and N,N-diphenylformamide (dpf)] was examined in the epoxidation of cis-cyclooctene with tert-butyl hydroperoxide(tbhp) at...

ver descrição completa

Detalhes bibliográficos
Autor principal: Gago, Sandra (author)
Outros Autores: Neves, Patrícia (author), Monteiro, Bernardo (author), Pessêgo, Márcia (author), Lopes, Andre D. (author), Valente, Anabela A. (author), Almeida Paz, Filipe A. (author), Pillinger, Martyn (author), Moreira, José (author), Silva, Carlos M. (author), Gonçalves, Isabel S. (author)
Formato: article
Idioma:eng
Publicado em: 2013
Assuntos:
Molybdenum
O ligands
Homogeneous catalysis
Epoxidation
Kinetics
Texto completo:http://hdl.handle.net/10400.1/3227
País:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/3227

Texto Completo

http://hdl.handle.net/10400.1/3227

Registos relacionados