Novel phosphovanadate layered structure assembled from a tetrametallic cubane-like V-v cluster

A novel phosphovanadate layered structure intercalated by 4,4 -bipyridinium cations, (C10H10N2)[(VO2)4(PO4)2], was synthesised under hydrothermal conditions and its crystal structure determined using single-crystal X-ray diffraction. The anionic [(VO2)4(PO4)2]n 2n− perforated layers are strongly hyd...

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Detalhes bibliográficos
Autor principal: Shi, FN (author)
Outros Autores: Paz, FAA (author), Rocha, J (author), Klinowski, J (author), Trindade, T (author)
Formato: article
Idioma:eng
Publicado em: 2004
Assuntos:
Texto completo:http://hdl.handle.net/10773/6022
País:Portugal
Oai:oai:ria.ua.pt:10773/6022