Electrogenerated nickel(I) complexes as catalysts for the intramolecular radical cyclisation of unsaturated a-bromoesters
The indirect electroreduction of unsaturated α-bromoesters using Ni(II) complexes as electron-transfer mediators is achieved in N,N'-dimethylformamide by constant current electrolysis between a cathode and a sacrificial anode in a diaphragmless cell. Cyclic compounds are obtained in moderate to...
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| Other Authors: | , , |
| Format: | article |
| Language: | eng |
| Published: |
2004
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| Subjects: | |
| Online Access: | http://hdl.handle.net/1822/3049 |
| Country: | Portugal |
| Oai: | oai:repositorium.sdum.uminho.pt:1822/3049 |