Electric polarization effects on the electronic spectral shift of centrosymmetric compounds

The classic dielectric dipolar Onsager model was extended to include quadrupolar interactions between solute molecules and solvents with different polarities. A multiparametric solvatochromic expression, based on the point quadrupole moment inside a spherical cavity embedded in a dielectric continuu...

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Bibliographic Details
Main Author: Togashi, Denisio M. (author)
Other Authors: Costa, Sílvia M. B. (author), Sobral, Abílio J. F. N. (author), Gonsalves, A. M. d'A. R. (author)
Format: article
Language:eng
Published: 2004
Subjects:
Quadrupole moment
Reaction field
Polarization
Dielectric
Solvatochromism
Online Access:http://hdl.handle.net/10316/5134
Country:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/5134

Internet

http://hdl.handle.net/10316/5134

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