Spatiotemporal control over the co-conformational switching in pH-responsive flavylium-based multistate pseudorotaxanes

A multistate molecular dyad containing flavylium and viologen units was synthesized and the pH dependent thermodynamics of the network completely characterized by a variety of spectroscopic techniques such as NMR, UV-vis and stopped-flow. The flavylium cation is only stable at acidic pH values. Abov...

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Bibliographic Details
Main Author: Diniz, Ana Marta (author)
Other Authors: Basílio, Nuno (author), Cruz, Hugo (author), Pina, Fernando (author), Parola, A Jorge (author)
Format: article
Language:eng
Published: 2016
Subjects:
Online Access:http://hdl.handle.net/10400.21/6395
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/6395