Cycloaddition reactions of nitrosoalkenes, azoalkenes and nitrile oxides mediated by hydrotalcite

Mg:Al 3:1 hydrotalcite (Ht), used in catalytic quantities, promotes the generation of nitrosoalkenes, azoalkenes and nitrile oxides. These can be intercepted in situ by heterocycles and olefins in [4+2] and [3+2] cycloaddition reactions, producing dihydro-1,2-oxazines, tetrahydropyridazines and isox...

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Bibliographic Details
Main Author: Lemos, A. (author)
Other Authors: Lourenço, J. P. (author)
Format: article
Language:eng
Published: 2012
Subjects:
Online Access:http://hdl.handle.net/10400.1/939
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/939