Homogeneous catalytic oxidation of styrene and styrene derivatives with hydrogen peroxide in the presence of transition metal-substituted polyoxotungstates

The tetrabutylammonium (TBA) salts of the Keggin-type polyoxotungstates with general formula [XW11M(H2O)O-39]((n-m)-), where X = P, B or Si and M = Mn, Fe or Co, were evaluated as catalysts in the oxidation of styrene, alpha-methylstyrene, p-methylstyrene, alpha,p-dimethylstyrene, p-chlorostyrene, p...

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Detalhes bibliográficos
Autor principal: Duarte, Tiago A. G. (author)
Outros Autores: Estrada, Ana C. (author), Simoes, Mario M. Q. (author), Santos, Isabel C. M. S. (author), Cavaleiro, Ana M. V. (author), Neves, M. Graca P. M. S. (author), Cavaleiro, Jose A. S. (author)
Formato: article
Idioma:eng
Publicado em: 1000
Assuntos:
BAEYER-VILLIGER OXIDATION
KEGGIN-TYPE POLYOXOTUNGSTATES
ONE-POT SYNTHESIS
SELECTIVE OXIDATION
SUPPORTED UNDECATUNGSTOPHOSPHATE
AROMATIC-ALDEHYDES
ACTIVE CATALYSTS
ALKENE OXIDATION
EPOXIDATION
BENZALDEHYDE
Texto completo:http://hdl.handle.net/10773/19834
País:Portugal
Oai:oai:ria.ua.pt:10773/19834

Texto Completo

http://hdl.handle.net/10773/19834

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