Electroreductive cyclisation of unsatured halides catalysed by nickel macrocyclic complexes

The indirect electroreduction of unsaturated aliphatic halides using Ni(II) complexes as electron-transfer mediators is achieved in N,N'-dimethylformamide by constant current electrolysis between a cathode and a sacrificial anode in a diaphragmless cell. Cyclic compounds are obtained in low to...

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Bibliographic Details
Main Author: Duñach, E. (author)
Other Authors: Esteves, Ana Paula (author), Freitas, A. M. (author), Medeiros, Maria José (author), Olivero, S. (author)
Format: article
Language:eng
Published: 1999
Subjects:
Electrochemical reactions
Cyclisation
Nickel and compounds
Radicals
Radical reaction
nickel
nickel compounds
Science & Technology
Online Access:http://hdl.handle.net/1822/3112
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/3112

Internet

http://hdl.handle.net/1822/3112

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