Molybdenum – and tungsten(II) monometallic 3-(2-pyridyl)pyrazole and bimetallic 3-(2-pyridyl)pyrazolate complexes

Molybdenum and tungsten complexes containing the pypzH (3-(2-pyridyl)pyrazole) ligand as a chelating bidentate are prepared: [Mo(CO)(4)(pypzH)], cis-[MoBr(eta(3)-allyl)(CO)(2)(pypzH)], cis-[MoCl(eta(3)-methallyl)(CO)(2)(pypzH)], [MI2(CO)(3)(pypzH)] (M = Mo, W) from [Mo(CO)(4)(NBD)] or the adequate b...

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Bibliographic Details
Main Author: Arroyo, Marta (author)
Other Authors: Miguel, Daniel (author), Villafane, Fernando (author), Alegria, Elisabete (author), Pombeiro, Armando (author)
Format: article
Language:eng
Published: 2015
Subjects:
Pyrazole-Derived Ligands
Metal-metal Interactions
Spectroscopic Properties
Crystal-Structure
Coordination Chemistry
Dynamic-Behavior
Hydrogen-Bond
Solid-State
Tetranuclear
Transition
Online Access:http://hdl.handle.net/10400.21/5112
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/5112

Internet

http://hdl.handle.net/10400.21/5112

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