Photoinduced reactivity in a Dispiro-1,2,4-trioxolane: Adamantane ring expansion and first direct observation of the long-lived triplet diradical intermediates
Dispiro-1,2,4-trioxolane, 1, an ozonide with efficient and broad antiparasitic activity, was synthesized and investigated using matrix isolation FTIR and EPR spectroscopies together with both B3LYP/6-311++G(3df, 3dp) and M06- 2X/6-311++G-(3df,3dp) theoretical methods. Irradiations (lambda >= 290...
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| Other Authors: | , , , , |
| Format: | article |
| Language: | eng |
| Published: |
2021
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| Subjects: | |
| Online Access: | http://hdl.handle.net/10400.1/16476 |
| Country: | Portugal |
| Oai: | oai:sapientia.ualg.pt:10400.1/16476 |