Bis(pyrazolyl)methanetetracarbonyl-molybdenum(0) as precursor to a molybdenum(VI) catalyst for olefin epoxidation

Bis(pyrazolyl) methanetetracarbonyl-molybdenum(0), cis-[Mo(CO)(4)(BPM)] (1), was prepared from Mo(CO)(6) and the ligand bis(pyrazolyl) methane (BPM), and examined as a catalyst precursor for the epoxidation of olefins using tert-butylhydroperoxide (TBHP) as oxidant. Catalytic activities followed the...

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Detalhes bibliográficos
Autor principal: Figueiredo, Sonia (author)
Outros Autores: Gomes, Ana C. (author), Fernandes, Jose A. (author), Almeida Paz, Filipe A. (author), Lopes, Andre D. (author), Lourenco, Joao P. (author), Pillinger, Martyn (author), Goncalves, Isabel S. (author)
Formato: article
Idioma:eng
Publicado em: 1000
Assuntos:
TERT-BUTYL HYDROPEROXIDE
TUNGSTEN COMPLEXES
CRYSTAL-STRUCTURES
CYCLOALKYL MOIETIES
DIOXO COMPLEXES
BRIDGING UNITS
ANSA COMPOUNDS
OXIDATION
LIGANDS
PEROXO
Texto completo:http://hdl.handle.net/10773/19537
País:Portugal
Oai:oai:ria.ua.pt:10773/19537

Texto Completo

http://hdl.handle.net/10773/19537

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