Epoxidation catalysts prepared by encapsulation of molybdenum hexacarbonyl in UiO-66(Zr/Hf)-type metal-organic frameworks

The confinement and catalytic behavior of Mo(CO)6 species inside UiO-66 (zirconium and hafnium) metalorganic frameworks (MOFs) have been investigated by means of multitechnique characterization and catalytic olefin epoxidation. Mo(CO)6 was encapsulated in nanocrystalline MOFs by solvothermal and vap...

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Bibliographic Details
Main Author: Gomes, Diana P. (author)
Other Authors: Silva, Andreia F. (author), Gomes, Ana C. (author), Neves, Patrícia (author), Valente, Anabela A. (author), Gonçalves, Isabel S. (author), Pillinger, Martyn (author)
Format: article
Language:eng
Published: 2022
Subjects:
Molybdenum hexacarbonyl
cis-Cyclooctene
Tert-butyl hydroperoxide
Metal-organic framework
Epoxidation
Online Access:http://hdl.handle.net/10773/34328
Country:Portugal
Oai:oai:ria.ua.pt:10773/34328

Internet

http://hdl.handle.net/10773/34328

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