Efficient preparation of graphene by combined intercalation : exfoliation steps

Despite the impressive improvements in the quality of large CVD- synthesized graphene sheets over the past years, the highest quality graphene layers are still obtained by mechanical exfoliation of pristine graphitic crystals. However, the method is notoriously tedious and gives a low yield. Worse s...

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Detalhes bibliográficos
Autor principal: Schellenberg, Peter Michael (author)
Outros Autores: Bernardo, César (author), Gonçalves, Hugo (author), Belsley, M. (author), Martins, José A. (author), Moura, C. (author), Stauber, Tobias Pascal (author)
Formato: conferencePoster
Idioma:eng
Publicado em: 2012
Assuntos:
Texto completo:http://hdl.handle.net/1822/19906
País:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/19906
Descrição
Resumo:Despite the impressive improvements in the quality of large CVD- synthesized graphene sheets over the past years, the highest quality graphene layers are still obtained by mechanical exfoliation of pristine graphitic crystals. However, the method is notoriously tedious and gives a low yield. Worse still, the graphene crystals are relatively small and large layers are often damaged by the exfoliation process itself. We wish to address these limitations and present a novel approach to prepare large graphene flakes with increased yield. To this end we combine the standard mechanical exfoliation with a chemical pretreatment of thegraphite crystals, while preserving the integrity of the graphene layers.