Oxidation of tertiary benzamides by 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride-tert-butylhydroperoxide
Tertiary benzamides are oxidized by the 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride-(BuOOH)-O-t system at the alpha-position of the N-alkyl groups. The major products are N-acylamides, although small amounts of secondary amides, the products of dealkylation, are also formed. Plots of initia...
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| Format: | article |
| Language: | eng |
| Published: |
2015
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| Online Access: | http://hdl.handle.net/10451/21325 |
| Country: | Portugal |
| Oai: | oai:repositorio.ul.pt:10451/21325 |