Oxidation of tertiary benzamides by 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride-tert-butylhydroperoxide

Tertiary benzamides are oxidized by the 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride-(BuOOH)-O-t system at the alpha-position of the N-alkyl groups. The major products are N-acylamides, although small amounts of secondary amides, the products of dealkylation, are also formed. Plots of initia...

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Detalhes bibliográficos
Autor principal: Constantino, L (author)
Outros Autores: Iley, J (author)
Formato: article
Idioma:eng
Publicado em: 2015
Assuntos:
Texto completo:http://hdl.handle.net/10451/21325
País:Portugal
Oai:oai:repositorio.ul.pt:10451/21325