Highly active phosphite gold(I) catalysts for intramolecular hydroalkoxylation, enyne cyclization and furanyne cyclization

New and highly active mononuclear phosphite gold(I) catalysts are described. Turn-over numbers up to 37 000 for the furanyne reaction and up to 28 000 000 for the two-fold hydroalkoxylation of alkynes are reported.

Bibliographic Details
Main Author: Maria Camila Blanco Jaimes (author)
Other Authors: Frank Rominger (author), Mariette M. Pereira (author), Rui M. B. Carrilho (author), Sónia A. C. Carabineiro (author), A. Stephen K. Hashmi (author)
Format: article
Language:eng
Published: 2014
Subjects:
Catálise homogénea, Química
Homogeneous catalysis, Chemical sciences
Online Access:https://hdl.handle.net/10216/106751
Country:Portugal
Oai:oai:repositorio-aberto.up.pt:10216/106751

Internet

https://hdl.handle.net/10216/106751

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