Semibatch operation and primary cyclization effects in homogeneous free-radical crosslinking copolymerizations
A theoretical analysis is presented on the use of semibatch reactors for producing non-linear copolymers through the homogeneous free-radical polymerization of mono- and divinyl-monomers. The kinetic scheme distinguishes two kinds of pendant double bonds and five kinds of polymer radicals, as it als...
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| Format: | article |
| Language: | eng eng |
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2008
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| Online Access: | http://hdl.handle.net/10198/340 |
| Country: | Portugal |
| Oai: | oai:bibliotecadigital.ipb.pt:10198/340 |