Unique Biradical Intermediate in the Mechanism of the Heme Enzyme Chlorite Dismutase

Funding Information: This research was supported by the grant NWO–CW 711.014.006 from the Council for Chemical Sciences of The Netherlands Organization for Scientific Research. S.T. acknowledges the support from the Project LISBOA-01-0145-FEDER-007660 (Microbiologia Molecular, Estrutural e Celular)...

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Detalhes bibliográficos
Autor principal: Püschmann, Julia (author)
Outros Autores: Mahor, Durga (author), De Geus, Daniël C. (author), Strampraad, Marc J.F. (author), Srour, Batoul (author), Hagen, Wilfred R. (author), Todorovic, Smilja (author), Hagedoorn, Peter Leon (author)
Formato: article
Idioma:eng
Publicado em: 2022
Assuntos:
biradical
chlorite dismutase
electron paramagnetic resonance spectroscopy
heme
microsecond-timescale freeze hyperquenching
rapid kinetics
resonance Raman spectroscopy
triplet state
Catalysis
Chemistry(all)
Texto completo:http://hdl.handle.net/10362/142216
País:Portugal
Oai:oai:run.unl.pt:10362/142216
Descrição
Resumo:Funding Information: This research was supported by the grant NWO–CW 711.014.006 from the Council for Chemical Sciences of The Netherlands Organization for Scientific Research. S.T. acknowledges the support from the Project LISBOA-01-0145-FEDER-007660 (Microbiologia Molecular, Estrutural e Celular) funded by FEDER funds through COMPETE 2020─Programa Operacional Competitividade e Internacionalização (POCI) and by national funds through FCT─Fundação para a Ciência e a Tecnologia and from the European Union’s Horizon 2020 Research and Innovation Program through TIMB3 (grant agreements no 810856). This work is dedicated to the late Prof. Simon de Vries, who pioneered the development of the rapid kinetic techniques that have been seminal in this study. Publisher Copyright: © 2021 The Authors. Published by American Chemical Society.

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