Unique Biradical Intermediate in the Mechanism of the Heme Enzyme Chlorite Dismutase

Funding Information: This research was supported by the grant NWO–CW 711.014.006 from the Council for Chemical Sciences of The Netherlands Organization for Scientific Research. S.T. acknowledges the support from the Project LISBOA-01-0145-FEDER-007660 (Microbiologia Molecular, Estrutural e Celular)...

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Bibliographic Details
Main Author: Püschmann, Julia (author)
Other Authors: Mahor, Durga (author), De Geus, Daniël C. (author), Strampraad, Marc J.F. (author), Srour, Batoul (author), Hagen, Wilfred R. (author), Todorovic, Smilja (author), Hagedoorn, Peter Leon (author)
Format: article
Language:eng
Published: 2022
Subjects:
biradical
chlorite dismutase
electron paramagnetic resonance spectroscopy
heme
microsecond-timescale freeze hyperquenching
rapid kinetics
resonance Raman spectroscopy
triplet state
Catalysis
Chemistry(all)
Online Access:http://hdl.handle.net/10362/142216
Country:Portugal
Oai:oai:run.unl.pt:10362/142216
Description
Summary:Funding Information: This research was supported by the grant NWO–CW 711.014.006 from the Council for Chemical Sciences of The Netherlands Organization for Scientific Research. S.T. acknowledges the support from the Project LISBOA-01-0145-FEDER-007660 (Microbiologia Molecular, Estrutural e Celular) funded by FEDER funds through COMPETE 2020─Programa Operacional Competitividade e Internacionalização (POCI) and by national funds through FCT─Fundação para a Ciência e a Tecnologia and from the European Union’s Horizon 2020 Research and Innovation Program through TIMB3 (grant agreements no 810856). This work is dedicated to the late Prof. Simon de Vries, who pioneered the development of the rapid kinetic techniques that have been seminal in this study. Publisher Copyright: © 2021 The Authors. Published by American Chemical Society.

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