Reactive vibrational excitation spectroscopy of formic acid in solid argon: Quantum yield for infrared induced trans→cis isomerization and solid state effects on the vibrational spectrum.
Formic acid molecules are trapped in two predominant local environments (sites) when isolated in an argon matrix at 8 K. Using narrowband tunable infrared (IR) radiation, we performed site-selective excitation of various vibrational modes of the lower-energy trans conformer. For all excited modes, r...
| Autor principal: | |
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| Outros Autores: | , , , , |
| Formato: | article |
| Idioma: | eng |
| Publicado em: |
2003
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| Texto completo: | http://hdl.handle.net/10316/17813 |
| País: | Portugal |
| Oai: | oai:estudogeral.sib.uc.pt:10316/17813 |