New chemistry of diazafulvenium methides: one way to pyrazoles

Diazafulvenium methides generated from the solution pyrolysis of pyrazolo[1,5-c][1,3]thiazole-2,2-dioxides participate in [8[pi]+2[pi]] cycloadditions giving pyrazolo[1,5-a]pyridine derivatives. 1-Methyl-diazafulvenium, generated under flash vacuum pyrolysis reaction conditions, undergoes an intramo...

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Detalhes bibliográficos
Autor principal: Melo, Teresa M. V. D. Pinho e (author)
Outros Autores: Soares, Maria I. L. (author), Gonsalves, António M. d'A. Rocha (author)
Formato: article
Idioma:eng
Publicado em: 2006
Assuntos:
Texto completo:http://hdl.handle.net/10316/5093
País:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/5093