Synthesis of new donor/acceptor 5-cyclopentadienyl and 5-indenyliron(II) complexes with p-benzonitrile derivatives. Crystal structures of [Fe( 5-C5H5)(CO)(P(OC6H5)3)(p-NCC6H4NO2)][BF4]·CH2Cl2 and [Fe( 5-C9H7)(CO)(P(OC6H5)3)(p-NCC6H4NO2)][BF4]

New complexes of the type [Fe( 5-Cp or Ind)(L)(L )(p-NCR)][BF4] (L, L =CO, P(OC6H5)3, P(C6H5)3; R=C6H4N(CH3)2, C6H4NO2, (E)-C(H) C(H)C6H4NO2, (E)-C(H) C(H)C6H4N(CH3)2) have been synthesised and characterised. Spectroscopic data were analysed in order to evaluate the tuning of the electronic density...

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Bibliographic Details
Main Author: Garcia, M. Helena (author)
Other Authors: Robalo, M. Paula (author), Teixeira, António P. S. (author), Dias, A. R. (author), Piedade, M. Fátima M. (author), Duarte, M. Teresa (author)
Format: article
Language:eng
Published: 2012
Subjects:
Iron complexes
Benzonitrile derivatives
Indenyl
Crystal structures
Cyclopentadienyl
Online Access:http://hdl.handle.net/10174/4025
Country:Portugal
Oai:oai:dspace.uevora.pt:10174/4025

Internet

http://hdl.handle.net/10174/4025

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