Homo-and heteropolymetallic 3-(2-pyridyl)pyrazolate manganese and rhenium complexes

fac-[MBr(CO)(3)(pypzH)] (M = Mn, Re; pypzH = (3-(2-pyridyl) pyrazole) complexes are prepared from fac[ MBr(CO)(3)(NCMe)(2)] and pypzH. The result of their deprotonation depends on the metallic substrate: the rhenium complex affords cleanly the bimetallic compound [fac-{Re(CO)(3)(mu(2)-pypz)}] 2 (mu(...

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Bibliographic Details
Main Author: Arroyo, Marta (author)
Other Authors: Gomez-Iglesias, Patricia (author), Anton, Noelia (author), Garcia-Rodriguez, Raul (author), Alegria, Elisabete (author), Pombeiro, Armando (author), Miguel, Daniel (author), Villafane, Fernando (author)
Format: article
Language:eng
Published: 2015
Subjects:
Tricarbonylrhenium(I) bromide complexes
Coordination compounds
Crystal structure
X-ray
Molecular structure
Electrochemical parametrization
Spectroscopic properties
Asymmetric catalysis
Pyrazole complexes
Ru(II) complexes
Online Access:http://hdl.handle.net/10400.21/4943
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/4943

Internet

http://hdl.handle.net/10400.21/4943

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