Bis(pyrazolyl)methanetetracarbonyl-molybdenum(0) as precursor to a molybdenum(VI) catalyst for olefin epoxidation

Bis(pyrazolyl)methanetetracarbonyl-molybdenum(0), cis-[Mo(CO)4(BPM)] (1), was prepared from Mo(CO)6 and the ligand bis(pyrazolyl)methane (BPM), and examined as a catalyst precursor for the epoxidation of olefins using tert-butylhydroperoxide (TBHP) as oxidant. Catalytic activities followed the seque...

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Bibliographic Details
Main Author: Figueiredo, Sónia (author)
Other Authors: Gomes, Ana C. (author), Fernandes, José A. (author), Paz, Filipe A. Almeida (author), Lopes, Andre D. (author), Lourenço, J. P. (author), Pillinger, Martyn (author), Gonçalves, Isabel S. (author)
Format: article
Language:eng
Published: 2013
Subjects:
Catalytic activity
Molybdenum
Bis(azolyl)methane ligands
Tetracarbonyl complexes
Oxidative decarbonylation
Olefin epoxidation
Online Access:http://hdl.handle.net/10400.1/2367
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/2367

Internet

http://hdl.handle.net/10400.1/2367

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