Rotational isomerism of acetic acid isolated in rare-gas matrices: Effect of medium and isotopic substitution on IR-induced isomerization quantum yield and cis→trans tunneling rate
Rotational isomerization of acetic acid (CH3COOH) is studied in Ar, Kr, and Xe matrices. The light-induced trans→cis reaction is promoted using resonant excitation of a number of modes in the 3500–7000 cm−1 region, and the quantum yields for this process are measured for various acetic acid isotopol...
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| Other Authors: | , , , |
| Format: | article |
| Language: | eng |
| Published: |
2004
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| Online Access: | http://hdl.handle.net/10316/17903 |
| Country: | Portugal |
| Oai: | oai:estudogeral.sib.uc.pt:10316/17903 |