Mu-Chlorido-Bridged Dimanganese(II) complexes of the schiff base derived from [2+2] condensation of 2,6-diformyl-4-methylphenol and 1,3-bis(3-aminopropyl)tetramethyldisloxane: structure, magnetismo, electrochemical behaviour, and catalytic oxidation of secondary alcohols

The reaction of 2,6-diformyl-4-methylphenol with 1,3-bis(3-aminopropyl)tetramethyldisiloxane in the presence of MnCl2 in a 1:1:2 molar ratio in methanol afforded a dinuclear -chlorido-bridged manganese(II) complex of the macrocyclic [2+2] condensation product (H2L), namely, [Mn2Cl2(H2L)(HL)]Cl cente...

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Bibliographic Details
Main Author: Alexandru, Mihaela (author)
Other Authors: Cazacu, Maria (author), Arvinte, Adina (author), Shova, Sergiu (author), Turta, Constantin (author), Simionescu, Bogdan C. (author), Dobrov, Anatolie (author), Alegria, Elisabete (author), Martins, Luisa (author), Pombeiro, Armando (author), Arion, Vladimir B. (author)
Format: article
Language:eng
Published: 2015
Subjects:
Manganese
Template Synthesis
Macrocycles
Schiff Bases
Oxidation
Online Access:http://hdl.handle.net/10400.21/4950
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/4950

Internet

http://hdl.handle.net/10400.21/4950

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