Valence tautomerism induced nucleophilic ipso substitution in a coordinated tetrabromocatecholate ligand and diverse catalytic activity mimicking the function of phenoxazinone synthase

Two new manganese(III) complexes, [pyH][Mn(Br(4)Cat)(2)(PY)1 (1) and [Mn(Br(4)Cat)(Br(3)PYCat)(PY)(2)] (2), where py is pyridine, Br(4)CatH(2) is tetrabromocatechol and Br(3)pyCatH(2) is 3,5,6-tribromo-4-pyridiniumcatechol, derived from redox 'noninnocent' bromo-substituted catecholate lig...

Full description

Bibliographic Details
Main Author: Panja, Anangamohan (author)
Other Authors: Jana, Narayan Ch (author), Patra, Moumita (author), Brandao, Paula (author), Moore, Curtis E. (author), Eichhorn, David M. (author), Frontera, Antonio (author)
Format: article
Language:eng
Published: 1000
Subjects:
ALGA ODONTHALIA-CORYMBIFERA
TRANSITION-METAL-COMPLEXES
COBALT(III) COMPLEXES
SUPEROXIDE-DISMUTASE
SEMIQUINONE LIGANDS
ORGANIC-CHEMICALS
CHEMISTRY
BROMOPHENOLS
ACTIVATION
OXIDATION
Online Access:http://hdl.handle.net/10773/19705
Country:Portugal
Oai:oai:ria.ua.pt:10773/19705

Internet

http://hdl.handle.net/10773/19705

Similar Items