Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate, the first example of an 3-heteroamatic-2H-azirine, was prepared and its reaction with conjugated 1,3-dienes, under mild conditions and in the absence of Lewis acid catalyst, produced cycloadducts in good yield and high stereoselectivity.
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| Other Authors: | , , |
| Format: | article |
| Language: | eng |
| Published: |
2005
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| Subjects: | |
| Online Access: | http://hdl.handle.net/1822/3419 |
| Country: | Portugal |
| Oai: | oai:repositorium.sdum.uminho.pt:1822/3419 |