Layered transition metal carboxylates: synthesis, structural aspects and observation of multi-step magnetic transition through phase diagram

Two new layered transition metal carboxylate frameworks, [Co-3(L)(2)(H2O)(6)]center dot 2H(2)O (1) and [Ni-3(L)(2)(H2O)(6)]center dot 2H(2)O (2) (L = tartronate anion or hydroxymalonic acid), have been synthesized and characterized by X-ray single crystal analysis. Both compounds have similar 2D str...

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Bibliographic Details
Main Author: Sen, Rupam (author)
Other Authors: Mal, Dasarath (author), Lopes, Armandina M. L. (author), Brandao, Paula (author), Araujo, Joao P. (author), Lin, Zhi (author)
Format: article
Language:eng
Published: 1000
Subjects:
ZEOLITIC IMIDAZOLATE FRAMEWORKS
ORGANIC FRAMEWORKS
HYDROTHERMAL SYNTHESIS
COORDINATION POLYMER
CRYSTAL-STRUCTURE
MIXED AZIDE
BEHAVIOR
TEMPERATURE
COPPER(II)
COMPLEXES
Online Access:http://hdl.handle.net/10773/19860
Country:Portugal
Oai:oai:ria.ua.pt:10773/19860

Internet

http://hdl.handle.net/10773/19860

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