Synthesis of diarylamines in the benzo[b]thiophene series bearing electron donating or withdrawing groups by Buchwald–Hartwig C–N coupling

Diarylamines in the benzo[b]thiophene series bearing electron donating or withdrawing groups, were prepared by Buchwald– Hartwig C–N coupling in moderate to high yields. The conditions used were Pd(OAc)2 (3 mol%), BINAP as ligand (4 mol%) and Cs2CO3 as base (1.4 equiv.), in toluene at 1008C, being 6...

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Bibliographic Details
Main Author: Ferreira, Isabel C.F.R. (author)
Other Authors: Queiroz, Maria João R.P. (author), Kirsch, Gilbert (author)
Format: article
Language:eng
Published: 2008
Subjects:
Online Access:http://hdl.handle.net/10198/818
Country:Portugal
Oai:oai:bibliotecadigital.ipb.pt:10198/818