Highly active and selective supported rhenium catalysts for aerobic oxidation of n-Hexane and n-Heptane

A series of derivative C-scorpionate rhenium complexes, i.e., [ReCl2{NNC(O)C6H5} (Hpz)(PPh3)2] (A) (where Hpz is pyrazole), [ReCl2{NNC(O)C6H5}(Hpz)2(PPh3)] (B), [ReClF {NNC(O)C6H5}(Hpz)2(PPh3)] (C), and their precursor [ReOCl3(PPh3)2] (D), immobilized on 3-aminopropyl-functionalized silica have been...

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Detalhes bibliográficos
Autor principal: Mishra, Gopal (author)
Outros Autores: Alegria, Elisabete (author), Pombeiro, Armando (author), Martins, Luisa (author)
Formato: article
Idioma:eng
Publicado em: 2018
Assuntos:
Rhenium
Scorpionate derivative
Immobilization
Supported catalysis
N-alkane
Oxidation
Molecular oxygen
Product selectivity
Radical mechanism
Texto completo:http://hdl.handle.net/10400.21/8278
País:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/8278

Texto Completo

http://hdl.handle.net/10400.21/8278

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