Highly active and selective supported rhenium catalysts for aerobic oxidation of n-Hexane and n-Heptane

A series of derivative C-scorpionate rhenium complexes, i.e., [ReCl2{NNC(O)C6H5} (Hpz)(PPh3)2] (A) (where Hpz is pyrazole), [ReCl2{NNC(O)C6H5}(Hpz)2(PPh3)] (B), [ReClF {NNC(O)C6H5}(Hpz)2(PPh3)] (C), and their precursor [ReOCl3(PPh3)2] (D), immobilized on 3-aminopropyl-functionalized silica have been...

Full description

Bibliographic Details
Main Author: Mishra, Gopal (author)
Other Authors: Alegria, Elisabete (author), Pombeiro, Armando (author), Martins, Luisa (author)
Format: article
Language:eng
Published: 2018
Subjects:
Rhenium
Scorpionate derivative
Immobilization
Supported catalysis
N-alkane
Oxidation
Molecular oxygen
Product selectivity
Radical mechanism
Online Access:http://hdl.handle.net/10400.21/8278
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/8278

Internet

http://hdl.handle.net/10400.21/8278

Similar Items