Tris(pyrazolyl)methane molybdenum tricarbonyl complexes as catalyst precursors for olefin epoxidation

The molybdenum tricarbonyl complexes [Mo(CO)3(HC(3,5-Me2pz)3)] (1) and [Mo(CO)3(HC(pz)3)] (2)(HC(3,5-Me2pz)3 = tris(3,5-dimethyl-1-pyrazolyl)methane, HC(pz)3 = tris(1-pyrazolyl)methane) were obtained in good yields by the microwave-assisted reaction of Mo(CO)6 with the respective organic ligand. Com...

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Bibliographic Details
Main Author: Gomes, Ana C. (author)
Other Authors: Neves, Patrícia (author), Figueiredo, Sónia (author), Fernandes, José A. (author), Valente, Anabela A. (author), Almeida Paz, Filipe A. (author), Pillinger, Martyn (author), Lopes, Andre D. (author), Gonçalves, Isabel S. (author)
Format: article
Language:eng
Published: 2016
Subjects:
Molybdenum
Tris(pyrazolyl)methane ligands
Homogeneous catalysis
Olefin epoxidation
Oxidative decarbonylation
Online Access:http://hdl.handle.net/10400.1/7962
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/7962

Internet

http://hdl.handle.net/10400.1/7962

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