Synthesis and electrochemical characterization of bimetallic ruthenium complexes with the bridging eta2(s,s)-1,3-butadiyne-1,4-diyl ligand
The bis(ruthenium)alkyne complex [cis-{RuCl (bpy)2(mu-C<FONT FACE="Symbol">º</FONT>C-)}]2 (1) was obtained by treatment of 1 equiv of either 1,4-bis(trimethylsilyl)-1,3-butadiyne or bis(trimetylsilyl)acetylene with 2 equiv of cis-[RuCl2(bpy)2].2H2O, NaF and NaBF4 salts in metha...
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| Other Authors: | , |
| Format: | article |
| Language: | eng |
| Published: |
2000
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| Subjects: | |
| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300009 |
| Country: | Brazil |
| Oai: | oai:scielo:S0103-50532000000300009 |