Improved Reactivity in the Ring-Opening Polymerization of ε-Caprolactone with a Trinuclear Titanium(IV) Oxochloroneopentoxide as Initiator

The complex [Ti3(O)(Cl)(ONep)9] and two iron(II)-containing products, [Fe4Cl8(thf)6] and [Fe2Cl3(thf)6][FeCl4], were synthesized by a redox reaction involving [Ti3(OiPr)11][FeCl4] and neopentanol; the structures of compounds [Ti3(O)(Cl)(ONep)9] and [Fe2Cl3(thf)6][FeCl4] have been confirmed by X-ray...

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Bibliographic Details
Main Author: Giese,Siddhartha O. K. (author)
Other Authors: Silva,Thiago A. da (author), Hughes,David L. (author), Rüdiger,André Luis (author), Sá,Eduardo L. de (author), Zawadzki,Sônia F. (author), Soares,Jaísa F. (author), Nunes,Giovana G. (author)
Format: article
Language:eng
Published: 2017
Subjects:
ε-caprolactone
titanium(IV)
trinuclear alkoxide
ring-opening polymerization
crystal structure analysis
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000801440
Country:Brazil
Oai:oai:scielo:S0103-50532017000801440

Internet

http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000801440

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