Improved Reactivity in the Ring-Opening Polymerization of ε-Caprolactone with a Trinuclear Titanium(IV) Oxochloroneopentoxide as Initiator

The complex [Ti3(O)(Cl)(ONep)9] and two iron(II)-containing products, [Fe4Cl8(thf)6] and [Fe2Cl3(thf)6][FeCl4], were synthesized by a redox reaction involving [Ti3(OiPr)11][FeCl4] and neopentanol; the structures of compounds [Ti3(O)(Cl)(ONep)9] and [Fe2Cl3(thf)6][FeCl4] have been confirmed by X-ray...

ver descrição completa

Detalhes bibliográficos
Autor principal: Giese,Siddhartha O. K. (author)
Outros Autores: Silva,Thiago A. da (author), Hughes,David L. (author), Rüdiger,André Luis (author), Sá,Eduardo L. de (author), Zawadzki,Sônia F. (author), Soares,Jaísa F. (author), Nunes,Giovana G. (author)
Formato: article
Idioma:eng
Publicado em: 2017
Assuntos:
ε-caprolactone
titanium(IV)
trinuclear alkoxide
ring-opening polymerization
crystal structure analysis
Texto completo:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000801440
País:Brasil
Oai:oai:scielo:S0103-50532017000801440

Texto Completo

http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000801440

Registros relacionados